助教 / Assistant Professor

信田 尚毅 (Naoki SHIDA)

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  • さえずり

Email: shida-naoki-gz [at] ynu.ac.jp 

Tel&FAX: 045-339-3945

Naoki Shida was born in Yamagata, Japan. After completing his B.S. at Yokohama National University, he perused his Ph.D research at Tokyo Institute of Technology under the supervision of Prof. Shinsuke Inagi with DC1 research fellowship from JSPS. His Ph.D thesis is on the gradient modification of material-surface by means of bipolar electrochemistry, and received Ph.D in 2016. During his time as a Ph.D student, he visited the group of Prof. Dwight S. Seferos at University of Toronto to explore the redox chemistry of chalcogenophene-containing small molecules and polymers.  He then worked as a postdoctoral scholar (Research Fellowship for Young Scientists, JSPS-PD) both at Tokyo University of Agriculture and Technology for Prof. Kazuhiro Chiba, and at California Institute of Technology for Prof. Theodor Agapie, respectively, to earn the expertise of organic and inorganic synthesis. In 2018, he started his academic career as a specially appointed assistant professor in the group of Prof. Shinsuke Inagi. From 2020, he join the Atobe group at Yokohama National University as an Assistant Professor. His research interest is the electrosynthesis (small molecules and polymers) and electrocatalysis. In a meantime, he is a family man, working out in the gym, and searching for shows in Netflix.

職歴/Employment

2020年10月~現在      横浜国立大学   大学院工学研究院   機能の創生部門 

2018年11月~2020年  9月 東京工業大学物質理工学院特任助教
2016年10月~2018年  4月 米国 California Institute of Technology博士研究員
2016年  4月~2018年10月 日本学術振興会特別研究員(PD)(東京農工大学)

2015年  7月~2015年  8月 カナダ University of Toronto訪問研究員

2013年  4月~2016年  3月 日本学術振興会特別研究員(DC1)

学歴/Education

2007年3月 日本大学山形高校卒業
2011年3月 横浜国立大学工学部卒業
2013年3月 東京工業大学大学院総合理工学研究科修士課程修了
2016年3月 東京工業大学大学院総合理工学研究科博士後期課程修了

博士(工学) -  東京工業大学

受賞/Awards

2021年 令和3年度有機電子移動化学奨励賞

2020年 第47回リバネス研究費 味の素ファインテクノ 機能性材料賞

2018年 The 13th International Symposium on Organic Reactions (ISOR-13) Excellent poster award

趣味/Hobby

子供と遊ぶこと、ジムに行くこと、動画鑑賞

​論文リスト/List of Publication

45. Yuto Ido, Atsushi Fukazawa, Yuka Furutani, Yasushi Sato, Naoki Shida,* Mahito Atobe*

Triple-phase Boundary in Anion-exchange Membrane (AEM) Reactor Enables Selective Electrosynthesis of Aldehyde from Primary Alcohol

ChemSusChem, Accepted (DOI: 10.1002/cssc.202102076)

44. Rio Mikami, Yuto Nakamura, Naoki Shida,* Mahito Atobe*

Anodic Substitution Reaction of Carbamates in a Flow Microreactor Using a Stable Emulsion Solution

Reaction Chemistry & Engineering, Accepted (DOI: 10.1039/D1RE00403D)

43. Joshua A. Buss,† Naoki Shida,† Tianyi He, Theodor Agapie*
Carbon Dioxide Reduction with Dihydrogen and Silanes at Low-Valent Molybdenum Terphenyl Diphosphine Complexes: Reductant Identity Dictates Mechanism

ACS Catalysis, Accepted (DOI: 10.1021/acscatal.1c02922)

† denotes equal contribution

42. Atsushi Fukazawa, Yugo Shimizu, Naoki Shida,* Mahito Atobe*

Electrocatalytic hydrogenation of benzoic acids in a proton-exchange membrane reactor

Organic & Biomolecular Chemistry, 2021, 19, 7363–7368 (DOI: 10.1039/D1OB01197A)

41. Naoki Shida, Elena Villani, Mokurai Sanuki, Kazuhiro Miyamoto, Akihiro Gotou, Tomohiro Isogai, Akiyoshi Yamauchi, Toshio Fuchigami, Ikuyoshi Tomita, Shinsuke Inagi*

Bipolar Electrochemical Fluorination of Triphenylmethane and Bis(phenylthio)diphenylmethane Derivatives in a U-shaped Cell

Electrochemistry, 2021, 89, 476–479 (DOI: 10.5796/electrochemistry.21-00074).

40. Naoki Shida,* Hiroaki Takenaka,  Akihiro Gotou, Tomohiro Isogai, Akiyoshi Yamauchi, Yosuke Kishikawa, Yuuya Nagata,  Ikuyoshi Tomita,  Toshio Fuchigami, Shinsuke Inagi*

Alkali Metal Fluorides in Fluorinated Alcohols: Fundamental Properties and Applications to Electrochemical Fluorination

Journal of Organic Chemistry, accepted (DOI: 10.1021/acs.joc.1c00821).

39. Yuki Naito, Yuto Nakamura, Naoki Shida, Hisanori Senboku, Kenta Tanaka,* Mahito Atobe*

Integrated Flow Synthesis of α-Amino Acids by in situ Generation of Aldimines and Subsequent Electrochemical Carboxylation

Journal of Organic Chemistry, accepted (DOI: 10.1021/acs.joc.1c00821).

38. Elena Villani, Naoki Shida, Shinsuke Inagi*

Electrogenerated Chemiluminescence of Luminol on Wireless Conducting Polymer Films

Electrochimica Acta, 2021, 389, 138718 (DOI: 10.1016/j.electacta.2021.138718).

37. Tomoki Hirohata, Naoki Shida, Hidehiro Uekusa, Nobuhiro Yasuda, Hirotomo Nishihara, Tomoki Ogoshi, Ikuyoshi Tomita, Shinsuke Inagi*

Pillar[6]quinone: Facile Synthesis, Crystal Structures and Electrochemical Properties

Chemical Communications, 2021, 57, 6360 (DOI: 10.1039/D1CC02413B).

Highlighted as a Front Cover

36. Yuto Nakamura, Yasushi Sato, Naoki Shida,* Mahito Atobe*

Electrochemical trimerization of catechol to 2,3,6,7,10,11-hexahydroxytriphenylene  using a flow microreactor  

Electrochemistry, 2021, 89, 395–399 (DOI: 10.5796/electrochemistry.21-00053).

35. Yaqian Zhou, Naoki Shida, Ikuyoshi Tomita, Shinsuke Inagi*

Fabrication of Gradient and Patterned Organic Thin Films by Bipolar Electrolytic Micelle Disruption Using Redox-active Surfactants

Angewandte Chemie International Edition, 2021, 60, 14620–14629 (DOI: 10.1002/anie.202103233).

34. Naoki Shida,* Yuto Nakamura, Mahito Atobe*

Electrosynthesis in Laminar Flow Using a Flow Microreactor

Chemical Record, 2021, 21, 2164– 2177 (DOI: 10.1002/tcr.202100016).

33. Tatsuya Suga, Naoki Shida,* Mahito Atobe*

Au-catalyzed Electrochemical Oxidation of Alcohols Using an Electrochemical Column Flow Cell

Electrochemistry Communications, 2021, 124, 106944 (DOI: 10.1016/j.elecom.2021.106944).

32. Tomoyuki Kurioka, Naoki Shida, Ikuyoshi Tomita, Shinsuke Inagi*

Post-Functionalization of Aromatic C-H Bonds at the Main Chains of π-Conjugated Polymers via Anodic Chlorination Facilitated by Lewis Acids

Macromolecules, 2021, 54, 3, 1539–1547 (DOI: 10.1021/acs.macromol.0c02556).

31. Naoki Shida, Kazuyuki Ninomiya, Natsuki Takigawa, Keiichi Imato, Yousuke Ooyama, Ikuyoshi Tomita, Shinsuke Inagi*

Diversification of Conjugated Polymers via Postpolymerization Nucleophilic Aromatic Substitution Reactions with Sulfur-, Oxygen-, and Nitrogen-based Nucleophiles

Macromolecules, 2021, 54, 725−735. (DOI: 10.1021/acs.macromol.0c02395)

30. Naoki Shida, Shinsuke Inagi*

Bipolar Electrochemistry in Synergy with Electrophoresis: Electric Field-driven Electrosynthesis of Anisotropic Polymeric Materials

Chemical Communications, 2020, 56, 14327-14336. (DOI: 10.1039/D0CC06204A)

Feature Article

Highlighted as a Front Cover

29. Yaqian Zhou, Naoki Shida, Yuki Koizumi, Kaoru Endo, Ikuyoshi Tomita, Shinsuke Inagi*
Fabrication of One-dimensional Polymer Nanowires by Templated Bipolar Electropolymerization Promoted by Electrophoretic Effect
Macromolecules, 2020, 53, 8123-8130. (DOI: 10.1021/acs.macromol.0c00873)

28. Naoki Shida, Satoshi Owaki, Hiroshi Eguchi, Takanobu Nishikawa, Ikuyoshi Tomita, Shinsuke Inagi*
Bis(pentafluorophenyl)-o-carborane and Its Arylthio Derivatives: Synthesis, Electrochemistry and Optical Properties
Dalton Transactions, 2020, 49, 12985-12989. (DOI: 10.1039/D0DT02205E)

Highlighted as a Back Cover

27. Naoki Shida, Honoka Nishimi, Yuki Asanuma, Ikuyoshi Tomita, Shinsuke Inagi*
Synthesis of a Conjugated Polymer with Ring-Fused Pyridinium Units via Post-polymerization Intramolecular Cyclization Reaction
Polymer Journal, 2020, 11, 4693-4698. (DOI: 10.1038/s41428-020-0388-8)

26. Naoki Shida, Tempei Watanabe, Ikuyoshi Tomita, Shinsuke Inagi*
Anisotropic Electrical Behavior of Poly(3,4-ethylenedioxythiophene) Films Fabricated by AC Bipolar Electropolymerization
Synthetic Metals, 2020, 266, 116439. (DOI: 10.1016/j.synthmet.2020.116439)

 

25. Feng Zheng, Sia-Er Tan, Yuki Yanamoto, Naoki Shida, Hiroki Nishiyama, Shinsuke Inagi, Ikuyoshi Tomita*
Preparation of a Germole-containing π-Conjugated Polymer by the Te-Li Exchange Reaction of a Tellurophene-containing Polymer
NPG Asia Materials,2020, 12, 41. (DOI: 10.1038/s41427-020-0224-9)

24. Katsutoshi Sekino, Naoki Shida, Ryosuke Shiki, Natsuki Takigawa, Hiroki Nishiyama, Ikuyoshi Tomita, Shinsuke Inagi*
Fluoride-Ion-Catalyzed Synthesis of Ladder-type Conjugated Benzobisbenzofurans via Intramolecular Nucleophilic Aromatic Substitution Reaction under Metal-free and Mild Conditions
Organic Letters,2020, 22, 2892-2896. (DOI: 10.1021/acs.orglett.0c00531)

Highlighted as a Supplementary Cover

Highlighted in Synfacts 2020, 16, 0534

23. Kazuyuki Ninomiya, Naoki Shida, Takanobu Nishikawa, Takuya Ishihara, Hiroki Nishiyama, Ikuyoshi Tomita, Shinsuke Inagi*
Postfunctionalization of a Perfluoroarene-containing π-Conjugated Polymer via Nucleophilic Aromatic Substitution Reaction
ACS Macro Letters,2020, 9, 284-289. (DOI: 10.1021/acsmacrolett.9b01020)

22. Naoki Shida, Yasushi Imada, Yohei Okada, Kazuhiro Chiba*
Mechanistic Insights on Concentrated Lithium Salt/Nitroalkane Electrolyte Based on Analogy with Fluorinated Alcohols
European Journal of Organic Chemistry,2020, 570-574. (DOI: 10.1002/ejoc.201901576)

† denotes equal contribution

21. Yaqian Zhou, Naoki Shida, Yuki Koizumi, Tempei Watanabe, Hiroki Nishiyama, Ikuyoshi Tomita, Shinsuke Inagi*
Template-free Perpendicular Growth of Poly(3,4-ethylenedioxythiophene) Fiber Array by Bipolar Electrolysis under Iterative Potential Application
Journal of Materials Chemistry C,2019, 7, 14745-14751. (DOI: 10.1039/C9TC04743C)

20. Naoki Shida, Hiroki Nishiyama, Feng Zheng, Shuyang Ye, Dwight S. Seferos, Ikuyoshi Tomita, Shinsuke Inagi*
Redox Chemistry of π-Extended Tellurophenes
Communications Chemistry, 2019, 2, 124. (DOI: 10.1038/s42004-019-0228-y)
Appeared in "Behind the Paper” by Nature Research Chemistry Community

19. Naoki Shida, Yaqian Zhou, Shinsuke Inagi*
Bipolar Electrochemistry: A Powerful Tool for Electrifying Functional Material Synthesis
Accounts of Chemical Research,2019, 52, 2598-2608. (DOI: 10.1021/acs.accounts.9b00337)

Highlighted as a Supplementary Cover

18. Feng Zheng, Yusuke Komatsuzaki, Naoki Shida, Hiroki Nishiyama, Shinsuke Inagi, Ikuyoshi Tomita*
Te-Li Exchange Reaction of Tellurophene-containing π-Conjugated Polymer as Potential Synthetic Tool for Functional π-Conjugated Polymers
Macromolecular Rapid Communications,2019, 40, 1900171. (DOI: 10.1002/marc.201900171)

17. Naoki Shida, Hiroki Nishiyama, Ikuyoshi Tomita, Shinsuke Inagi*
Layer-by-layer Multilayered Film Formation on Gradient Polyelectrolyte Brush Prepared by Bipolar Electrochemistry
Chemistry Letters,2019, 48, 1174-1177. (DOI: 10.1246/cl.190461)

16. Kazuhiro Okamoto, Naoki Shida, Mizuki Tsutsui, Kazuhiro Chiba*
Liquid-phase Synthesis of N-Functionalized Azanucleoside-incorporated Oligonucleotides and Development of Anodic C(sp3)-H Acetoxylation Reaction for Direct Preparation of Azaribose
Synlett, 2019, 30, 1303-1307. (DOI: 10.1055/s-0037-1611550)

15. Yasushi Imada, Naoki Shida, Yohei Okada, Kazuhiro Chiba*
A Novel Thermomorphic System for Electrocatalytic Diels‐Alder Reactions
Chinese Journal of Chemistry, 2019, 37, 557-560. (DOI: 10.1002/cjoc.201900053)

14. Naoki Shida, Yasushi Imada, Shingo Nagahara, Yohei Okada, Kazuhiro Chiba*
Interplay of Arene Radical Cations with Anions and Fluorinated Alcohols in Hole Catalysis
Communications Chemistry, 2019, 2, 24. (DOI: 10.1038/s42004-019-0125-4)
Appeared in “Behind the Paper” by Nature Research Chemistry Community

13. Kazuhiro Okamoto, Shoji Takao, Mizuki Tsutsui, Naoki Shida, Kazuhiro Chiba*
Synthesis of Ribo-azanucleosides by Anodic Oxidation: Reactivity Control of Intermediate for Short-step Access to Pharmacophore
Chemistry - A European Journal, 2018, 24, 17902-17905. (DOI: 10.1002/chem.201804285)

12. Naoki Shida, Joshua A. Buss, Theodor Agapie*
Mild Electrochemical Synthesis of Metal Phosphides with Dibenzo-7-phosphanorbornadiene Derivatives: Mechanistic Insights and Application to Proton Reduction in Water
Chemical Communications, 2018, 54, 767-770. (DOI: 10.1039/C7CC09003J)

 

11. Yasushi Imada, Yusuke Yamaguchi, Naoki Shida, Yohei Okada, Kazuhiro Chiba*
Entropic Electrolyte for Anodic Cycloaddition of Unactivated Alkene Nucleophiles
Chemical Communications, 2017, 53, 3960-3963. (DOI: 10.1039/c7cc00664k)

10. Naoki Shida, Daichi Okazaki, Tomoyuki Kurioka, Hiroki Nishiyama, Dwight S. Seferos, Ikuyoshi Tomita, Shinsuke Inagi*
Anodic Chlorination of Selenophene-containing Polymers: Reaction Efficiency and Selective Reaction of Single-segment in Rod-rod Diblockcopolymer
ChemElectroChem, 2017, 4, 1824-1827. (DOI: 10.1002/celc.201700205)

Highlighted as an Inside Cover

9. Junji Suzuki, Naoki Shida, Shinsuke Inagi, Toshio Fuchigami*
Electrochemical Properties and Reactions of Organoboronic Acids in the Presence of Fluoride Ions
Electroanalysis, 2016, 28, 2797-2801. (DOI: 10.1002/elan.201600130)

8. Shunsuke Kuribayashi, Naoki Shida, Shinsuke Inagi, Toshio Fuchigami*
Synthesis of Fluorinated Triazole and Isoxazole Derivatives by Electrochemical Fluorination
Tetrahedron, 2016, 72, 5343-5349.(DOI: 10.1016/j.tet.2016.07.016)

7. Yuki Koizumi, Naoki Shida, Masato Ohira, Hiroki Nishiyama, Ikuyoshi Tomita, Shinsuke Inagi*
Electropolymerization on Wireless Electrodes towards Conducting Polymer Microfibre Networks
Nature Communications, 2016, 7, 10404. (DOI: 10.1038/ncomms10404)

6. Naoki Shida, Fusao Kitamura, Toshio Fuchigami, Hiroki Nishiyama, Ikuyoshi Tomita, Shinsuke Inagi*
Signal-Amplified Analysis of Molecular Layers Made by Bipolar Electrochemistry
ChemElectroChem, 2016, 3, 465-471. (DOI: 10.1002/celc.201500350)

5. Naoki Shida, Yuki Koizumi, Hiroki Nishiyama, Ikuyoshi Tomita, Shinsuke Inagi*
Electrochemically Mediated Atom Transfer Radical Polymerization from a Substrate Surface Manipulated by Bipolar Electrolysis: Fabrication of Gradient and Patterned Polymer Brushes
Angewandte Chemie International Edition, 2015, 54, 3922-3926. (DOI: 10.1002/anie.201412391)

Selected as a Hot Paper, highlighted as a Front Cover

4. Yuki Koizumi, Naoki Shida, Ikuyoshi Tomita, Shinsuke Inagi*
Bifunctional Modification of Conductive Particles by Iterative Bipolar Electro- deposition of Metals
Chemistry Letters, 2014, 43, 1245-1247. (DOI: 10.1246/cl.140387)

3. Shinsuke Inagi,* Kohei Hosoi, Tatsuya Kubo, Naoki Shida, Toshio Fuchigami
o-Carborane-Triphenylamine Dyad: Studies on Its Acceptor-Donor Behavior toward Dual Redox Mediator
Electrochemistry, 2013, 81, 368-370. (DOI: 10.5796/electrochemistry.81.368)

2. Shinsuke Inagi,* Yutaka Ishiguro, Naoki Shida, Toshio Fuchigami
Measurements of Potential on and Current through Bipolar Electrode in U-type Electrolytic Cell with a Shielding Wall
Journal of The Electrochemical Society, 2012, 159, G146-G150. (DOI: 10.1149/2.021212jes)

1. Naoki Shida, Yutaka Ishiguro, Mahito Atobe, Toshio Fuchigami, Shinsuke Inagi*
Electro-Click Modification of Conducting Polymer Surface Using Cu(I) Species Generated on a Bipolar Electrode in a Gradient Manner
ACS Macro Letters, 2012, 1, 656-659. (DOI: 10.1021/mz300210w)

著書

4. 跡部真人・信田 尚毅

「有機電解反応の現状とフロー技術の利用」  

フローマイクロ合成の最新動向, シーエムシー出版, pp. 53-59 (2021)   

3. Mahito Atobe, Naoki Shida

Development of Novel Organic Electrosynthetic Processes Using Electrochemical Flow Microreactor (book chapter of "Middle Molecular Strategy")

pp 297-308, Springer, 2021 (link)

2. Shinsuke Inagi, Naoki Shida

Electrosynthesis of Functional Polymer Materials
Modern Electrosynthetic Methods in Organic Chemistry, F. Marken and M. Atobe (eds.), CRC Press, Chapter 6, pp 127-148 (2018)

1. Shinsuke Inagi, Naoki Shida, Toshio Fuchigami

Electrochemical Doping of Polyaniline Using Bipolar Electrode
Trends in Polyaniline Research, Nova Science Publishers, Inc., Chapter 5, pp.95-105 (2013)

総説・解説

4. 「注目の論文:電気と光でC-H機能化」

信田尚毅

​月刊化学, vol.76, No.8 (2021) (link)

3. 固体高分子電解質電解技術が拓く新たな有機電解合成プロセス

跡部 真人・深澤 篤・信田 尚毅

触媒, Vol. 63, No.3 (2021)

2. タンデム式超音波乳化法が拓く新たなポリマーナノ粒子合成

跡部 真人・越野 美春・白石 幸秀・信田 尚毅

化学工学, 84巻, 4号 (2021)

1. 信田尚毅,稲木信介,高分子レドックス化学に基づく傾斜ポリマーブラシの開発
化学工業, 69, 11月号, 793-798 (2018)

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